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Periodic Classification of Elements

Class 10 Science • Complete Chapter Notes

1. Introduction

As the number of known elements increased, scientists needed a systematic way to organise them. Elements have different physical and chemical properties, but some elements also show similarities in their properties.

Classification helps us study a large number of elements by placing elements with similar characteristics in an organised pattern.

Key idea: The periodic classification of elements is an attempt to find a systematic relationship between the properties of elements and their atomic structure.

2. Early Classification of Elements

One of the earliest classifications divided the known elements broadly into metals and non-metals.

As more elements were discovered, scientists looked for better methods that could group elements according to similarities in their properties.

Important Historical Attempts

3. Döbereiner's Triads

In 1817, Johann Wolfgang Döbereiner, a German chemist, identified groups of three elements having similar properties. These groups were called triads.

Main Rule of a Triad

When the three elements are arranged in increasing order of atomic mass, the atomic mass of the middle element is approximately the average of the atomic masses of the other two elements.

Approximate atomic mass of middle element

= (Atomic mass of first element + Atomic mass of third element) ÷ 2

Example: Li, Na and K

Element Atomic Mass
Lithium (Li) 6.9
Sodium (Na) 23.0
Potassium (K) 39.0
Average of Li and K
= (6.9 + 39.0) ÷ 2
≈ 22.95
which is close to the atomic mass of Na (23.0).

Other Examples

Some groups such as Ca-Sr-Ba and Cl-Br-I also illustrate the idea of triads.

Limitations of Döbereiner's Triads

4. Newlands' Law of Octaves

John Newlands arranged elements in increasing order of atomic masses.

He observed that every eighth element had properties similar to the first element, similar to the repetition found in musical octaves.

Law of Octaves: When elements are arranged in increasing order of atomic masses, the properties of every eighth element are similar to those of the first element.

Limitations

5. Mendeleev's Periodic Table

Dmitri Ivanovich Mendeleev arranged elements mainly on the basis of increasing atomic masses and similarities in their chemical properties.

Mendeleev's Periodic Law

The properties of elements are a periodic function of their atomic masses.

Major Features

Importance of Prediction

Leaving gaps was an important strength of Mendeleev's table. It allowed him to predict that undiscovered elements should exist and estimate some of their properties.

Limitations

6. Modern Periodic Law

The modern periodic table is based on atomic number rather than atomic mass.

Modern Periodic Law: The properties of elements are periodic functions of their atomic numbers.

Atomic number is the number of protons present in the nucleus of an atom.

7. Modern Periodic Table

The modern periodic table arranges elements according to increasing atomic number and their recurring chemical properties.

Groups

The vertical columns of the periodic table are called groups.

The modern periodic table has 18 groups.

Periods

The horizontal rows of the periodic table are called periods.

The modern periodic table has 7 periods.

Remember: Vertical columns = Groups
Horizontal rows = Periods

8. Position of an Element in the Modern Periodic Table

The electronic configuration of an element helps us understand its position in the periodic table.

Period Number

The number of occupied electron shells generally indicates the period of an element.

Valence Electrons

The electrons present in the outermost shell are called valence electrons.

Group and Valence Electrons

For many main-group elements, the number of valence electrons is related to their group position and helps explain their chemical behaviour.

9. Valency

Valency is the combining capacity of an atom.

It is related to the number of electrons involved in achieving a stable outer electronic configuration.

General Trend Across a Period

For many main-group elements, valency tends to increase from one to four and then decrease from four to zero as we move across a period.

Exam idea: Do not memorise valency separately without understanding the outer electronic configuration.

10. Atomic Size

Atomic size refers broadly to the size of an atom and is commonly represented using its atomic radius.

Across a Period

Atomic size generally decreases from left to right across a period.

This is because the nuclear charge increases while the electrons are added to the same principal shell, increasing the effective attraction between the nucleus and electrons.

Down a Group

Atomic size generally increases from top to bottom in a group because new electron shells are added.

Trend: Across a period → Atomic size generally decreases.
Down a group → Atomic size generally increases.

11. Metallic Character

Metallic character describes the tendency of an element to show metallic properties and lose electrons to form positive ions.

Across a Period

Metallic character generally decreases from left to right.

Down a Group

Metallic character generally increases down a group.

Simple trend: Metallic character is generally higher towards the lower-left side of the periodic table and lower towards the upper-right side.

12. Non-Metallic Character

Non-metallic character is associated with the tendency of an element to gain or share electrons rather than lose them easily.

Across a Period

Non-metallic character generally increases from left to right.

Down a Group

Non-metallic character generally decreases down a group.

Trend: Non-metallic character generally increases towards the upper-right region of the periodic table.

13. Reactivity and Position in the Periodic Table

The position of an element in the periodic table is related to its electronic configuration and therefore influences its chemical reactivity.

Metals

Metals generally react by losing electrons. Down many groups of metals, increasing atomic size can make removal of the outermost electron easier, so metallic reactivity can increase down the group.

Non-Metals

Non-metals generally tend to gain or share electrons. Their tendency to attract electrons is influenced by atomic size and effective nuclear attraction.

Exam connection: Periodic trends should be understood through atomic size, electronic configuration and nuclear attraction rather than memorised as isolated arrows.

14. Periodic Trends Summary

Property Across a Period Down a Group
Atomic size Generally decreases Generally increases
Valency Generally increases to 4, then decreases to 0 Similar valence-shell pattern within a main group
Metallic character Generally decreases Generally increases
Non-metallic character Generally increases Generally decreases

15. Important Terms

Atomic Number: Number of protons present in the nucleus of an atom.
Atomic Mass: The relative mass assigned to an atom based on the masses of its constituent particles and the isotopic composition used for the element.
Valence Electrons: Electrons present in the outermost occupied shell.
Valency: Combining capacity of an atom.
Group: Vertical column in the modern periodic table.
Period: Horizontal row in the modern periodic table.

16. Historical Classification at a Glance

Scientist / System Basis Main Idea
Döbereiner Atomic mass and similar properties Triads
Newlands Increasing atomic mass Law of Octaves
Mendeleev Atomic mass and chemical properties Periodic table with gaps for undiscovered elements
Modern Periodic Table Atomic number Periodic relationship of properties

17. Quick Revision

Döbereiner
Triads
Newlands
Law of Octaves
Mendeleev
Periodic table based mainly on atomic mass
Modern Periodic Law
Properties are periodic functions of atomic number
Groups
Vertical columns
Periods
Horizontal rows
Atomic Size
Decreases across a period, increases down a group
Metallic Character
Decreases across a period, increases down a group

18. Exam Focus

Official Study Sources

For the most current curriculum, students should use the official CBSE Academic material and the official NCERT textbook resources.

CBSE Academic – Curriculum 2026-27 CBSE – Class X Science Reading Material 2026-27 CBSE – Science Learning Standards CBSE – Class 10 Science Competency-Based Questions NCERT – Official Textbooks